42175-50-8Relevant academic research and scientific papers
The chemistry of poly(trifluoromethyl)benzenes. Part II. Reactions of 1,2,3,5-tetrakis(trifluoromethyl)benzene with organolithium compounds
Dmowski, W.,Porwisiak, J.,Krajewski, J.,Mishnyov, A.,Kemme, A.
, p. 15 - 23 (1993)
1,2,3,5-Tetrakis(trifluoromethyl)benzene reacts with phenyl-lithium or t-butyl-lithium to give mixtures of de-aromatised products, derivatives of 2,5- and 2,4-cyclohexadiene-1-ylidene of molecular composition C10H2F10Ph2, C10H2F9Ph3, C10H2F10Bu2t and C10H3F10But.The X-ray crystal structure of the triphenyl derivative has been obtained.The 1H, 19F and 13C NMR data provide a satisfactory proof for the structures of the other compounds.
