42300-58-3Relevant academic research and scientific papers
The synthesis of sulfinylphthalimides and their reactions with some nucleophiles in dioxane
Bozkurt, Yasemin Soydas,Kutuk, Halil
body text, p. 2250 - 2257 (2012/03/27)
In this study, some N-(p-substituted-arylsulfinyl)phthalimides (1a-1e) were synthesized. The synthesized compounds were examined with respect to their substitution reactions with sodium ethoxide, sodium methoxide, methylamine, and t-butylamine in dioxane.
p-Tolylsulfinyl Amides: Reagents for Facile Electrophilic Functionalization of Olefins
Krasnova, Larissa B.,Yudin, Andrei K.
, p. 2584 - 2587 (2007/10/03)
A variety of olefins were found to react with sulfinyl amides in the presence of POCl3 to give β-chlorosulfides and β-hydroxysulfides in good yields. In the absence of nucleophiles, p-tolylsulfinyl amides were found to react with olefins with the formation of allylsulfoxides.
Kinetics and mechanisms of the acid-catalyzed hydrolyses of N-(4-substituted-arylsulfinyl)phthalimides
Kutuk, Halil,Bekdemir, Yunus,Soydas, Yasemin
, p. 224 - 228 (2007/10/03)
The acid-catalyzed hydrolyses of N-(4-substituted-arylsulfinyl)phthalimides were studied in aqueous solutions of perchloric and sulfuric acids at 50.0 ± 0.1 and of hydrochloric acid at 40.0 ± 0.1°C. Analysis of the data by the Cox-Yates excess acidity method and substituent, temperature and solvent isotope effects indicate hydrolysis by an A2 mechanism at low acidity. At higher acidities a changeover to an A1 mechanism is observed. Copyright
