42409-86-9Relevant academic research and scientific papers
Samarium(II) Diiodide Mediated Coupling of Bis(bromomethyl)arenes. Facile Synthesis of n>Cyclophanes without using High-Dilution Techniques
Takahashi, Senji,Mori, Nobuo
, p. 2029 - 2032 (2007/10/02)
In the presence of samarium(II) diiodide (Sml2), coupling of 1,3- and 1,4-bis(bromomethyl)benzenes proceeds smoothly to give their cyclic and acyclic oligomers.Use of 1.2 equiv. of Sml2 gives 1,2-bis(3- and 4-bromomethylphenyl)ethanes, respectively, in 95percent yield, and the use of 5.0 equiv. of Sml2 affords n>metacyclophanes and n>paracyclpphanes (n = 2, 3 and 4), respectively, in satisfactory yields.By using 5.0 equiv. of Sml2, 2-bromo- and 2-methoxy-1,4-bis(bromomethyl)benzenes and 1,4- and 2,6-bis(bromomethyl)naphthalenes each give only one of several expected isomeric cyclophanes as the major cyclic oligomer.
NEW SYNTHETIC METHOD OF PARACYCLOPHANE, BENZOCYCLOBUTENE, AND LEPIDOPTRENE: PYROLYSIS OF ARYLMETHYL PHENYL SELENIDES
Higuchi, Hiroyuki,Sakata, Yoshiteru,Misumi, Soichi,Otsubo, Tetsuo,Ogura, Fumio,Yamaguchi, Hachiro
, p. 627 - 630 (2007/10/02)
The flash vacuum pyrolysis of benzyl phenyl selenides gave bibenzyls and diphenyl diselenide in excellent yields.This type of reaction was successfully applied to the synthesis of the title compounds.
