425369-75-1Relevant academic research and scientific papers
Chiral discrimination in the intramolecular abstraction of allylic hydrogens by benzophenone triplets
Bosca, Francisco,Andreu, Inmaculada,Morera, Isabel M.,Samadi, Abdelouahid,Miranda, Miguel A.
, p. 1592 - 1593 (2007/10/03)
Using two diastereomeric compounds containing benzophenone and olefin units, significant chiral discrimination has been found in all the photophysical and photochemical processes involved in intramolecular hydrogen abstraction: overall quenching of benzophenone triplets, actual hydrogen abstraction step and π-quenching.
Stereoselective intramolecular hydrogen abstraction by a chiral benzophenone derivative
Miranda, Miguel A.,Martinez, Luis A.,Samadi, Abdelouahid,Bosca, Francisco,Morera, Isabel M.
, p. 280 - 281 (2007/10/03)
An unprecedented stereoselective photoreduction of a chiral BZP is observed in steady state as well as in time-resolved studies.
