425429-10-3Relevant academic research and scientific papers
Reductive opening of carbohydrate phenylsulfonylethylidene (PSE) acetals
Chéry, Florence,Cabianca, Elena,Tatibou?t, Arnaud,De Lucchi, Ottorino,Lindhorst, Thisbe K.,Rollin, Patrick
, p. 117 - 124 (2015/10/28)
The phenylsulfonylethylidene (PSE) acetal is a relatively new protecting group in carbohydrate chemistry. However, carbohydrate-derived phenylsulfonylethylidene (PSE) acetals show a different behavior in reductive desulfonylation than simple symmetrical a
A general, selective synthesis of ω-hydroxyethenyl ethers
Cabianca,Chéry,Rollin,Tatibou?t,De Lucchi
, p. 585 - 587 (2007/10/03)
A general selective synthesis of β-, γ- and δ-hydroxyethenyl ethers, a class of compounds containing two mutually reactive functionalities positioned at an interacting distance, is based on the reaction of diols with 1,2-bis-(phenylsulfonyl)ethylene (BPSE) followed by reductive elimination of the resulting β-phenylsulfonyl acetals with sodium amalgam.
