42565-25-3

Basic information

• Product Name: (Z)-3,4-Bis(4-methoxyphenyl)-3-hexen
• Synonyms: (Z)-3,4-Bis(4-methoxyphenyl)-3-hexen
• CAS NO: 42565-25-3
• Molecular Weight: 296.409
• Mol File: 42565-25-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (Z)-3,4-Bis(4-methoxyphenyl)-3-hexen(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3,4-Bis(4-methoxyphenyl)-3-hexen(42565-25-3)
• EPA Substance Registry System: (Z)-3,4-Bis(4-methoxyphenyl)-3-hexen(42565-25-3)

Safety Data

• Hazardous Substances Data: 42565-25-3(Hazardous Substances Data)

Upstream product

• 56-53-1 diethylstilbestrol 
• 77-78-1 dimethyl sulfate 
• 121-97-1 4-Methoxypropiophenone 
• 130-80-3 3,4-bis-(4-propionyloxy-phenyl)-hex-3c-ene 

Relevant articles and documents

InCl3-Zn. A novel reduction system for the deoxygenative coupling of carbonyl compounds to olefins

A simple and inexpensive procedure for the deoxygenative homo-coupling and cross-coupling of carbonyl compounds with InCl3-Zn system in dry acetonitrile at ambient pressure is achieved. The procedure gives excellent yields of E-olefinic products.

Stereochemistry and Side Products in Reductive Coupling of Alkyl Aryl Ketones to 1,2-Dialkyl-1,2-diarylethylenes

The reductive coupling of alkyl aryl ketones 1 - 3 and 7 - 9 by low valent titanium salts yields predominantly the (Z)-isomers of 11 - 13 and 17 - 19.Evidence is given by 1H NMR spectroscopy.This behavior can be explained by ?-complex formation of phenyl rings with Ti0.Severe steric hindrance, however, favors the (E)-isomers ( -> 14 and 15).Donor groups in p-position, particularly, give increasing amounts of pinacols, 23 - 27, which undergo rearrangement to the ketones 28 and 29.