426822-59-5Relevant academic research and scientific papers
Fast method for synthesis of alkyl and aryl-N-methylnitrones
Yavuz, Serkan,Ozkan, Hamdi,Colak, Naki,Yildirir, Yilmaz
experimental part, p. 6677 - 6683 (2011/10/31)
A simple, fast, efficient and eco-friendly procedure was developed for the synthesis of alkyl and aryl-N-methylnitrones. The corresponding nitrones of aromatic aldehydes, aliphatic aldehydes and alicyclic carbonyl compounds were prepared from N-methylhydr
Dialkylzinc-Assisted Alkynylation of Nitrones
Pinet, Sandra,Pandya, Shashi Urvish,Chavant, Pierre Yves,Ayling, Alexander,Vallee, Yannick
, p. 1463 - 1466 (2007/10/03)
(matrix presented) Reaction of nitrones with terminal alkynes takes place readily in the presence of a substoichiometric amount of diethylzinc in toluene, affording N-propargyl-hydroxylamines in excellent yields and purity.
Asymmetric Induction in the Addition of Grignard Reagents to Nitrones
Cowling, Martin P.,Jenkins, Paul R.,Cooper, Kelvin
, p. 1503 - 1504 (2007/10/02)
Grignard reagents add to N-(2-phenylpropylidene)cyclohexanamine N-oxide with significant asymmetric induction; an X-ray structure of one product demonstrates that the addition proceeds according to Cram's rule.
