426841-92-1Relevant academic research and scientific papers
Copper-catalyzed asymmetric hydrogenation of 2-substituted ketones: Via dynamic kinetic resolution
Zatolochnaya, Olga V.,Rodríguez, Sonia,Zhang, Yongda,Lao, Kendricks S.,Tcyrulnikov, Sergei,Li, Guisheng,Wang, Xiao-Jun,Qu, Bo,Biswas, Soumik,Mangunuru, Hari P. R.,Rivalti, Daniel,Sieber, Joshua D.,Desrosiers, Jean-Nicolas,Leung, Joyce C.,Grinberg, Nelu,Lee, Heewon,Haddad, Nizar,Yee, Nathan K.,Song, Jinhua J.,Kozlowski, Marisa C.,Senanayake, Chris H.
, p. 4505 - 4510 (2018)
A new class of tunable heterophosphole dimeric ligands have been designed and synthesized. These ligands have enabled the first examples of Cu-catalyzed hydrogenation of 2-substituted-1-tetralones and related heteroaryl ketones via dynamic kinetic resolut
Pd-Catalyzed Stereoselective 1,2-Aryboration of Alkenylarenes
Zhang, Penglin,Xing, Mimi,Guan, Qitao,Zhang, Jinguo,Zhao, Qian,Zhang, Chun
, p. 8106 - 8109 (2019)
The palladium-catalyzed highly regio- and diastereoselective arylboration of alkenylarenes has been developed. This chemistry afforded the benzylic boronic esters with a broad substrate scope, which are valuable synthetic intermediates for organic synthes
NOVEL CHIRAL DIHYDROBENZOAZAPHOSPHOLE LIGANDS AND SYNTHESIS THEREOF
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Paragraph 0167; 0168, (2018/06/15)
This invention relates to novel phosphorous ligands useful for organic transformations. Methods of making and using the ligands in organic synthesis are described. The invention also relates to processes for preparing the novel ligands.
Diastereoselective Friedel-Crafts alkylation of hydronaphthalenes
Tsoung, Jennifer,Kraemer, Katja,Zajdlik, Adam,Liebert, Clemence,Lautens, Mark
experimental part, p. 9031 - 9045 (2011/12/21)
An efficient and versatile synthesis of chiral tetralins has been developed using both inter- and intramolecular Friedel-Crafts alkylation as a key step. The readily available hydronaphthalene substrates were prepared via a highly enantioselective metal-c
Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Organoboronic Acids
Lautens, Mark,Dockendorff, Chris,Fagnou, Keith,Malicki, Adrianna
, p. 1311 - 1314 (2007/10/03)
(Equation Presented) The first rhodium(I)-catalyzed asymmetric addition of organoboronic acids to oxabicyclic alkenes is reported. This asymmetric ring-opening (ARO) reaction can proceed in high yield under very mild conditions with electronically diverse
