4278-92-6Relevant academic research and scientific papers
On the way to an oxidative Hosomi-Sakurai reaction
Sabot, Cyrille,Commare, Bruno,Duceppe, Marc-Alexandre,Nahi, Salima,Guérard, Kimiaka C.,Canesi, Sylvain
experimental part, p. 3226 - 3230 (2009/06/06)
An oxidative allylation process mediated by a hypervalent iodine reagent has been performed on polysubstituted phenols. This reaction, occurring in useful to good yields, leads to a rapid access to dienones containing a quaternary carbon center. Georg Thieme Verlag Stuttgart.
Electron transfer induced dissociations of 2- and 4-alkyl cyclohexadienones
McCarroll, Andrew J.,Crayston, Joe A.,Walton, John C.
, p. 4275 - 4280 (2007/10/03)
Several 2- and 4-alkylcyclohexadienones were prepared and shown to accept electrons to produce ketyl radical anions that dissociated rapidly at room temperature to release carbon-centered radicals and an aromatic phenoxide type anion. In the PET process with benzyl-substituted cyclohexadienones, initiated with triethylamine, the benzyl radicals dimerised or abstracted an H-atom from solvent. In electrochemical reductions, and in reductions with alkali metals in liquid ammonia, the benzyl radicals were further reduced to anions.
