428822-28-0Relevant academic research and scientific papers
A pseudo-cage complex of silver(I) with tripodal tetraamine having benzyl end groups, {tris[2-(benzylamino)-ethyl]amine-κ4N}silver(I) perchlorate
Yoon, Il,Shin, Yong Woon,Kim, Jineun,Park, Ki-Min,Park, Sung Bae,Lee, Shim Sung
, p. m165-m166 (2002)
The synthesis and crystal structure of {tris[2-(benzylamino)-ethyl]amine-κ4N}silver(I) perchlorate, [Ag(C27H36N4)]ClO4 or [Ag(bz3tren)]ClO4 {bz3tren is tris[2-(benzylamino)ethyl]-amine or N,N′,N″-tribenzyltris(2-aminoethyl)amine} are reported. The Ag atom is coordinated to four N atoms of the tren unit and is located 0.604 (3) A out of the trigonal plane described by the three secondary amine N atoms, away from the bridgehead N atom. Edge-to-face π-π interactions between the aromatic end groups, and weak interactions between Ag and arene, allow the formation of a pseudo-cage complex.
