42883-88-5Relevant academic research and scientific papers
Anodic Oxidation of Vinyl Sulphides. A Convenient Synthesis of α-Thiolated Aldehydes
Matsumoto, Akiteru,Suda, Kohji,Yijima, Chino
, p. 263 (1981)
Anodic Oxidation of vinyl sulphides in aqueous acetonitrile gives α-thiolated aldehydes in good yields.
Photoredox β-thiol-α-carbonylation of enones accompanied by unexpected Csp2-C(CO) bond cleavage
Du, Ding,Feng, Jie,Ma, Rui,Zhang, Beichen,Zhang, Kuili
supporting information, p. 7549 - 7553 (2020/10/13)
An olefinic difunctionalization method of enones was presented hereviaaerobic visible-light catalysis. A novel reactivity was showcased in conjunction with the selective Csp2-C(CO) bond activation of enones, which provided a convenient method for the preparation of various β-thiolated-α-functionalized compounds. Moreover, the preliminary investigation of the mechanism indicated that a β-peroxysulfide intermediate was formed under the promotion of visible light under an oxygen atmosphere, which finally induced the unexpected C-C bond cleavage.
