430-49-9Relevant academic research and scientific papers
FLUORINATION OF ACRYLATE ESTERS AND DERIVATIVES
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Paragraph 0043, (2013/03/26)
The present invention generally relates to processes for converting acrylate esters or a derivative thereof to difluoropropionic acid or a derivative thereof. This process is generally performed using fluorine gas in a hydrofluorocarbon solvent.
SYNTHESIS OF 2-FLUOROPROPENOIC ACID DERIVATIVES
Tolman, Vladimir,Spronglova, Pavla
, p. 319 - 326 (2007/10/02)
A method is described for the synthesis of 2-fluoropropenoic acid esters, amides, and nitrile from the corresponding derivatives of 2-fluoro-3-(4-toluenesulfonyloxy)propanoic acid by heating with potassium phtalimide in vacuo.The free acid Ia and its chloride have also been synthetized.The reactivity of esters and nitrile of acid Ia has been verified by the Michael addition of diethyl acetamidomalonate to these compounds.
