431875-39-7Relevant academic research and scientific papers
1-Diisopropylaminophospholes: Synthesis and X-ray characterisations of new palladium and platinum complexes
Hydrio, Jér?me,Gouygou, Maryse,Dallemer, Frédéric,Balavoine, Gilbert G.A,Daran, Jean-Claude
, p. 19 - 26 (2007/10/03)
Starting from palladium precursor [Pd(CH3CN)2Cl2], 1-diisopropylaminophospholes give dinuclear complexes, [Pd(phosphole)Cl2]2, which proved to be intermediates in the formation of mononuclear complexes, cis-[Pd(phosphole)2Cl2]. In contrast with the platinum precursor, only mononuclear complexes, [Pt(phosphole)2Cl2], are obtained with both cis and trans configurations. These new complexes were fully characterised by X-ray crystallography.
