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43226-07-9

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43226-07-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 43226-07-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 4,3,2,2 and 6 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 43226-07:
(7*4)+(6*3)+(5*2)+(4*2)+(3*6)+(2*0)+(1*7)=89
89 % 10 = 9
So 43226-07-9 is a valid CAS Registry Number.

43226-07-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name N-(2-methylcyclohexyl)benzamide

1.2 Other means of identification

Product number -
Other names naringetol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:43226-07-9 SDS

43226-07-9Downstream Products

43226-07-9Relevant articles and documents

Metallaphotoredox-Catalyzed Cross-Electrophile Csp3-Csp3 Coupling of Aliphatic Bromides

Smith, Russell T.,Zhang, Xiaheng,Rincón, Juan A.,Agejas, Javier,Mateos, Carlos,Barberis, Mario,García-Cerrada, Susana,De Frutos, Oscar,Macmillan, David W. C.

supporting information, p. 17433 - 17438 (2019/01/04)

A strategy for the installation of small alkyl fragments onto pharmaceutically relevant aliphatic structures has been established via metallaphotoredox catalysis. Herein, we report that tris(trimethylsilyl)silanol can be employed as an effective halogen abstraction reagent that, in combination with photoredox and nickel catalysis, allows a generic approach to Csp3-Csp3 cross-electrophile coupling. In this study, we demonstrate that a variety of aliphatic drug-like groups can be successfully coupled with a number of commercially available small alkyl electrophiles, including methyl tosylate and strained cyclic alkyl bromides. Moreover, the union of two secondary aliphatic carbon centers, a long-standing challenge for organic molecule construction, has been accomplished with a wide array of structural formats. Last, this technology can be selectively merged with Csp2-Csp3 aryl-alkyl couplings to build drug-like systems in a highly modular fashion.

A direct and stereoretentive synthesis of amides from cyclic alcohols

Mondal, Deboprosad,Bellucci, Luca,Lepore, Salvatore D.

, p. 7057 - 7061 (2012/01/03)

Chlorosulfites prepared in situ using thionyl chloride react with nitrile complexes of titanium(IV) fluoride to give a one-pot conversion of alcohols into amides. For the first time, amides are obtained from cyclic alcohols with stereoretention. Critical to the design of these new TiIV reactions has been the use of little-explored TiIV nitrile complexes that are thought to chelate chlorosulfites in the transition state tocreate a carbocation that is rapidly captured by the nitrile nucleophile through a front-side attack mechanism.

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