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4324-23-6

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4324-23-6 Usage

Uses

Bis(triphenyltin)?selenide is a mild and selective reagent used in the preparation of symmetrical α-?selenoesters.

Check Digit Verification of cas no

The CAS Registry Mumber 4324-23-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,3,2 and 4 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 4324-23:
(6*4)+(5*3)+(4*2)+(3*4)+(2*2)+(1*3)=66
66 % 10 = 6
So 4324-23-6 is a valid CAS Registry Number.

4324-23-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name BIS(TRIPHENYLTIN)SELENIDE

1.2 Other means of identification

Product number -
Other names Silane,diphenylbis(triphenylstannyl)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4324-23-6 SDS

4324-23-6Downstream Products

4324-23-6Relevant articles and documents

Fluorodestannylation. A Powerful Technique to Liberate Anions of Oxygen, Sulfur, Selenium, and Carbon

Harpp, David N.,Gingras, Marc

, p. 7737 - 7745 (2007/10/02)

Fluoride ions smoothly destannylate organotin chalcogenides to liberate nucleophilic chalcogenide ions; hence the first nucleophilic oxide (O2-) and selenide (Se2-) transfer agents are reported where the tin atom serves as "group 16 (VIB) transfer agent".In the presence of crown ethers or ammonium salts, this process results in a new way to generate "naked" nucleophiles.Ethers and selenides are formed in good to excellent yield.In addition, a useful C-C bond-forming reaction has been developed by using alkyltins with aldehydes and acid chlorides in the presence of fluroide ion.Aspects concerning reactivity and mechanism are presented.Finally, the generality of the fluorodestannylation procedure and the differences with parallel silicon chemistry are detailed.

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