433725-50-9

Basic information

• Product Name: trans-[NiCl(4-C₄N₂ClF₂)(PCy₃)2]
• CAS NO: 433725-50-9
• Molecular Weight: 804.518
• Mol File: 433725-50-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[NiCl(4-C₄N₂ClF₂)(PCy₃)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[NiCl(4-C₄N₂ClF₂)(PCy₃)2](433725-50-9)
• EPA Substance Registry System: trans-[NiCl(4-C₄N₂ClF₂)(PCy₃)2](433725-50-9)

Safety Data

• Hazardous Substances Data: 433725-50-9(Hazardous Substances Data)

Upstream product

• 2622-14-2 tricyclohexylphosphine 

Relevant articles and documents

Aromatic C-F activation at Ni in the presence of a carbon-chlorine bond: The nickel mediated synthesis of new pyrimidines

Treatment of [Ni(COD)2]/PCy3 with 5-chloro-2,4,6-trifluoropyrimidine affords the C-F activation product trans-[NiF(4-C4N2ClF2)(PCy3) 2] 2, which reacts with iodine to form 5-chloro-2,6-difluoro-4-iodo-pyrimidine 5.