4342-28-3Relevant academic research and scientific papers
A strikingly fast route to methylmercury acetylides as a new opportunity for monomethylmercury detection
Lombardo, Marco,Vassura, Ivano,Fabbri, Daniele,Trombini, Claudio
, p. 588 - 593 (2005)
Methylmercury σ-complexation to 1-alkynes is exploited in a new practical and sensitive quantitation of monomethylmercury in water and in biological tissues; indeed, methylmercury halides are detected at the nanomolar level by 10-(3-trimethylsilyl-2-propynyl)-9-(10H)-acridinone, in dichloromethane and in the presence of Bu4NF·3H2O.
REACTIONS OF ORGANOMERCURY FULMINATES WITH ACETYLENE DERIVATIVES
Sarlo, Francesco De,Guarna, Antonio,Goti, Andrea,Brandi, Alberto
, p. 115 - 122 (2007/10/02)
Organomercury fulminates react with acetylene derivatives to give unstable 3-(organomercurio)isoxazoles, which isomerize to 2-cyanoenolates.These are hydrolyzed with hydrochloric acid to the corresponding enols and are cleaved by water at the double bond.With monosubstituted acetylenes, substitution at the free position by the organomercury residue is predominant.
