434284-31-8

Basic information

• Product Name: (+/-)-(1R^*,2R^*,9S^*)-8-methyltricyclo<7.3.1.0^2,7>tridec-7-en-13-one
• Synonyms: (+/-)-(1R^*,2R^*,9S^*)-8-methyltricyclo<7.3.1.0^2,7>tridec-7-en-13-one
• CAS NO: 434284-31-8
• Molecular Weight: 204.312
• Mol File: 434284-31-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+/-)-(1R^*,2R^*,9S^*)-8-methyltricyclo<7.3.1.0^2,7>tridec-7-en-13-one(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(1R^*,2R^*,9S^*)-8-methyltricyclo<7.3.1.0^2,7>tridec-7-en-13-one(434284-31-8)
• EPA Substance Registry System: (+/-)-(1R^*,2R^*,9S^*)-8-methyltricyclo<7.3.1.0^2,7>tridec-7-en-13-one(434284-31-8)

Safety Data

• Hazardous Substances Data: 434284-31-8(Hazardous Substances Data)

Upstream product

• 1614-94-4 2-hydroxy-8-methyl-tricyclo<7.3.1.0^2,7>tridecan-13-one 
• 1614-94-4 (+/-)-(1R^*,2S^*,7S^*,9S^*)-2-hydroxy-8-methyltricyclo<7.3.1.0^2,7>tridecan-13-one 

Relevant articles and documents

Synthesis and isomerization of tricyclo[7.3.1.02,7]tridecen-13-ones

Dehydration of 2-hydroxy-8-R-tricyclo[7.3.1.02,7]tridecan-13-ones (R = H, Me, Ph) effected by various reagents provided 8-R-tricyclo[7.3.1.02,7]tridecen-13-ones with different positions of the double bond. In the presence of phosphoric acid arise isomers with the double bond in 2(3) position, a mixture of hydrochloric and acetic acid primarily affords isomers with the double bond in 2(7) position that further migrates into 7(8) position at R = Me, Ph.