4359-18-6

Basic information

• Product Name: 1,3,5-Cycloheptatriene, 7-(phenylsulfonyl)-
• CAS NO: 4359-18-6
• Molecular Formula: C13H12O2S
• Molecular Weight: 232.303
• Mol File: 4359-18-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3,5-Cycloheptatriene, 7-(phenylsulfonyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Cycloheptatriene, 7-(phenylsulfonyl)-(4359-18-6)
• EPA Substance Registry System: 1,3,5-Cycloheptatriene, 7-(phenylsulfonyl)-(4359-18-6)

Safety Data

• Hazardous Substances Data: 4359-18-6(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 27081-10-3 tropylium tetrafluoroborate 
• 1538-96-1 α-diazomethyl phenyl sulfone 
• 5726-14-7 7-phenylthiocycloheptatriene 

Downstream Products

• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 35387-59-8 1,2-Bis(phenylsulfonyl)ethylene 
• 66030-84-0 Benzenesulfonic acid benzenesulfonylmethyl ester 

Relevant articles and documents

Addition of Arylsulphonylcarbenes to Benzene

Arylsulphonylcarbenes have been generated in benzene by thermolysis of arylsulphonyldiazomethanes.Contrary to previous findings arylsulphonylcarbenes and to benzene giving the corresponding arylsulphonylcycloheptatrienes.

Some stable substituted cycloheptatrienyl carbanions

The reaction of some 7-substituted cycloheptatrienes with KNH2 in liquid ammonia is described.In several cases stable carbanions are formed.Their NMR spectra are consistent with a non-planar pentadienyl-like structure.A comparison of the 1H-NMR spectra of 10 and 11 shows the paratropic character of the cycloheptatrienyl anions.