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4360-47-8

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4360-47-8 Usage

Chemical Properties

Cinnamonitrile, transcinnamonitrile is a colorless, crystalline solid (mp 23.5-24°C) or a colorless, viscous liquid with a spicy, slightly floral odor. Cinnamonitrile can be prepared by one of the common routes to nitriles, for example, by dehydration of cinnamaldoxime. It is stable to alkali and is used for perfuming soaps and detergents.

Trade name

Cinnamalva (IFF)

Check Digit Verification of cas no

The CAS Registry Mumber 4360-47-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,3,6 and 0 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 4360-47:
(6*4)+(5*3)+(4*6)+(3*0)+(2*4)+(1*7)=78
78 % 10 = 8
So 4360-47-8 is a valid CAS Registry Number.
InChI:InChI=1/C9H7N/c10-8-4-7-9-5-2-1-3-6-9/h1-7H/b7-4-

4360-47-8 Well-known Company Product Price

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  • Alfa Aesar

  • (A15301)  Cinnamonitrile, cis + trans, 97%   

  • 4360-47-8

  • 25g

  • 673.0CNY

  • Detail
  • Alfa Aesar

  • (A15301)  Cinnamonitrile, cis + trans, 97%   

  • 4360-47-8

  • 100g

  • 1176.0CNY

  • Detail
  • Alfa Aesar

  • (A15301)  Cinnamonitrile, cis + trans, 97%   

  • 4360-47-8

  • 500g

  • 4853.0CNY

  • Detail

4360-47-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Cinnamonitrile

1.2 Other means of identification

Product number -
Other names 2-Propenenitrile,3-phenyl-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4360-47-8 SDS

4360-47-8Relevant articles and documents

Synthetic Methods and Reactions; 83. Sulfuryl Chloride Fluoride, a Mild Dehydrating Agent in the Preparation of Nitriles from Aldoximes

Olah, George A.,Narang, Subhash C.,Garcia-Luna, Armando

, p. 659 (1980)

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Highly diastereoselective aziridination of imines with trimethylsilyldiazomethane. Subsequent silyl substitution with electrophiles, ring opening, and metalation of C-silylaziridines - A cornucopia of highly selective transformations

Aggarwal, Varinder K.,Alonso, Emma,Ferrara, Marco,Spey, Sharon E.

, p. 2335 - 2344 (2002)

Treatment of a range of N-sulfonyl (Ts and SES) imines derived from aromatic, heteroaromatic, aliphatic, and unsaturated aldehydes with trimethylsilydiazomethane gave C-silylaziridines in good yield (32-83%) and with high diastereoselectivity in favor of the cis product (80:20-100:0). In contrast, an α-imino ester gave predominantly the trans-aziridine (89:11) in high yield (91%). The synthetic potential of C-silylaziridines was investigated. Treatment with F- (tetrabutylammonium triphenyldifluorosilicate was used) in the presence of aldehydes gave the α-hydroxyaziridines in high yield and high diastereoselectivity (86:14-98:2) for the newly created stereogenic center. Complete retention of configuration was observed in the substitution of the silyl group with electrophiles in all cases. Trapping with deuterium (using CDCl3 as electrophile) was also successful, but trapping with phosphate [using CIP(O)(OPh)2] and acetate (using Ac2O) was unsuccessful. In these latter cases ring opening by chloride and acetate, respectively, was observed. Further ring-opening reactions were effected using azide and thiolate nucleophiles and in all cases complete regioselectivity in favor of attack at the silyl-bearing carbon occurred. Complete regioselectivity was also observed in the carbonylative ring expansion using Co2(CO)8 to give a β-lactam. Treatment of cis-1-tosyl-2-phenyl/butyl-3-trimethylsilylaziridines with n-BuLi and subsequent quenching with MeI followed completely different pathways, depending on the 2-substituent. In the case of the 2-phenylaziridine, metalation was initiated α to the phenyl group and led finally to a fused tricyclic adduct with four stereogenic centers as a single diastereoisomer. In the case of the 2-butylaziridine, metalation occurred α to the silyl group and led to a trisubstituted silylaziridine, probably via an azirine intermediate.

Palladium N-methylimidazolium supported complexes as efficient catalysts for the Heck reaction

Altava, Belen,Burguete, M. Isabel,Garcia-Verdugo, Eduardo,Karbass, Naima,Luis, Santiago V.,Puzary, Amrit,Sans, Victor

, p. 2311 - 2314 (2006)

Different N-methylimidazolium supported ligands have been easily synthesized. The palladium complexes derived from those materials can be used for the catalysis of the Heck reaction giving excellent yields, selectivities and very good TON and TOF values. The supported Pd-pincer complexes show an increased stability, and provide a clear improvement in the recovery and reuse for the supported catalysts.

Pd(0) supported onto monolithic polymers containing IL-like moieties. Continuous flow catalysis for the Heck reaction in near-critical EtOH

Karbass, Naima,Sans, Victor,Garcia-Verdugo, Eduardo,Burguete, M. Isabel,Luis, Santiago V.

, p. 3095 - 3097 (2006)

Long-term stable Pd(0) catalysts can be easily supported onto polymeric monoliths containing methyl-imidazole moieties and the corresponding reactors based on these materials can be applied for the continuous Heck reaction in near-critical EtOH. The Royal Society of Chemistry 2006.

A new reagent for efficient synthesis of nitriles from aldoximes using methoxymethyl bromide

ULUDAG, Nesimi,GIDEN, Ozge NUR

, p. 993 - 998 (2021/02/05)

This study outlines an efficient, high-yielding, and rapid method by which to access diverse nitriles from aldoximes with methoxymethyl bromide (MOM-Br) in THF. It represents the first application of MOM-Br as a deoximation reagent to synthesize nitriles. The reaction was performed at reflux to ensure excellent yield (79-96%) of the nitriles within 20-45 minutes. Furthermore, this method has been successfully applied to the synthesis of the synthesis precursor of aromatic, heteroaromatic, cyclic, and acyclic aliphatic.

A new palladium heterogeneous complex (Pd-Gu@BOEH): chemoselective, phosphine-free and practical nanocatalyst in carbon–carbon cross-coupling reaction

Jafari, Fariba,Ghorbani-Choghamarani, Arash,Hasanzadeh, Neda

, p. 1033 - 1049 (2020/11/05)

Herein, boehmite nanoparticles were synthesized via combination of Al(NO3)3·9H2O and NaOH in aqueous solution. This nanomaterial converted to Pd-Gu@BOEH in several sequences. Pd-Gu@BOEH was used as efficient and recoverable nanocatalyst for the chemoselective C–C band formation such as Mizoroki–Heck and Suzuki–Miyaura reactions without any phosphine ligands or inert atmosphere. This catalyst has been characterized by several analyses such as EDS, WDX, SEM, XRD, FT-IR, TEM, TGA, AAS and BET. Also, obtained products from C–C coupling reactions were identified by NMR spectroscopy and their melting points. This catalyst was recycled in described reactions without palladium leaching. The reused catalyst was characterized by EDS, WDX, XRD, FT-IR and AAS analysis, which showed good stability during reaction process.

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