436145-58-3

Basic information

• Product Name: 1,3-Propanediol, 2-methyl-2-(2-pyridinyl)-, bis(4-methylbenzenesulfonate) (ester)
• CAS NO: 436145-58-3
• Molecular Formula: C23H25NO6S2
• Molecular Weight: 475.587
• Mol File: 436145-58-3.mol

Chemical Properties

• CAS DataBase Reference: 1,3-Propanediol, 2-methyl-2-(2-pyridinyl)-, bis(4-methylbenzenesulfonate) (ester)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Propanediol, 2-methyl-2-(2-pyridinyl)-, bis(4-methylbenzenesulfonate) (ester)(436145-58-3)
• EPA Substance Registry System: 1,3-Propanediol, 2-methyl-2-(2-pyridinyl)-, bis(4-methylbenzenesulfonate) (ester)(436145-58-3)

Safety Data

• Hazardous Substances Data: 436145-58-3(Hazardous Substances Data)

Upstream product

• 199984-57-1 2-(1,3-dihydroxy-2-methylpropan-2-yl)pyridine 
• 98-59-9 p-toluenesulfonyl chloride 
• 68888-19-7 6-(hydroxymethyl-ethyl)pyridine 
• 100-71-0 2-Ethylpyridine 

Downstream Products

• 1451062-20-6 6-methyl-6-(pyridin-2-yl)-1,4-ditosyl-1,4-diazepane 
• 1451062-32-0 6-methyl-6-(pyridin-2-yl)-1,4-bis[2-(pyridin-2-yl)ethyl]-1,4-diazepane 

Relevant articles and documents

Enhancement in catalytic proton reduction by an internal base in a diiron pentacarbonyl complex: its synthesis, characterisation, inter-conversion and electrochemical investigation

The reaction of a tripodal ligand (H2L) with a {S2N} donor-set with tri-iron dodecacarbonyl in toluene leads to the isolation of a diiron pentacarbonyl complex 1 as a model for the sub-site of the [FeFe]-hydrogenase. Protonation of this complex under CO (1 atm.) forms quantitatively the hexacarbonyl complex 2H+ with a pendant pyridinium group. Infrared spectroscopic investigations indicate that its pendant pyridinium group dissociates to give hexacarbonyl complex 2 which forms subsequently the pentacarbonyl complex 1. The electrochemistry of these complexes has been investigated. Complex 2H+ exhibits electrocatalysis on proton reduction at a potential more positive by over 200 mV compared to that for other neutral diiron hexacarbonyl complexes. This catalysis is enhanced under a CO atmosphere by freeing the bound base group which acts as a proton relay in the catalysis.

Copper(II), iron(II), and manganese(II) complexes of 2-methyl-2-(2- pyridinyl)-1,3-propanediamine

Copper(II), iron(II), and manganese(II) complexes of 2-methyl-2-(2- pyridinyl)-1,3-propanediamine (ppda) were synthesized and characterized. The reaction of copper(II), iron(II), or manganese(II) salts with ppda yields complexes [Cu(ppda)Cl2] (

Selective Ruthenium-Catalyzed Transformation of Carbon Dioxide: An Alternative Approach toward Formaldehyde

Formaldehyde is an important precursor to numerous industrial processes and is produced in multimillion ton scale every year by catalytic oxidation of methanol in an energetically unfavorable and atom-inefficient industrial process. In this work, we present a highly selective one-step synthesis of a formaldehyde derivative starting from carbon dioxide and hydrogen gas utilizing a homogeneous ruthenium catalyst. Here, formaldehyde is obtained as dimethoxymethane, its dimethyl acetal, by selective reduction of carbon dioxide at moderate temperatures (90 °C) and partial pressures (90 bar H2/20 bar CO2) in the presence of methanol. Besides the desired product, only methyl formate is formed, which can be transformed to dimethoxymethane in a consecutive catalytic step. By comprehensive screening of the catalytic system, maximum turnover numbers of 786 for dimethoxymethane and 1290 for methyl formate were achieved with remarkable selectivities of over 90% for dimethoxymethane.

Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand

The novel tridentate diamidoamine ligands [RC(2-C5H4N)(CH2NSiMe3) 2]2- (R = H, CH3) have been synthesized and coordinated to TiIV and ZrIV giving the pentac