436161-78-3Relevant academic research and scientific papers
Unusually low barrier to carbamate C-N rotation
Deetz, Martin J.,Forbes, Christopher C.,Jonas, Marco,Malerich, Jeremiah P.,Smith, Bradley D.,Wiest, Olaf
, p. 3949 - 3952 (2002)
The barrier for rotation about an N-alkylcarbamate C(carbonyl)-N bond is around 16 kcal/mol. In the case of an N-phenylcarbamate, the rotational barrier is lowered to 12.5 kcal/mol, but with N-(2-pyrimidyl)carbamates the barriers are so low (9 kcal/mol)
