436808-45-6Relevant articles and documents
α-iminoenamido ligands: A novel structure for transition-metal activation
Kim, Young Heui,Kim, Tae Ho,Lee, Bun Yeoul,Woodmansee, David,Bu, Xianhui,Bazan, Guillermo C.
, p. 3082 - 3084 (2008/10/08)
This communication shows that it is possible to activate nickel complexes containing the α-iminoenamide ligand using B(C6F5)3 or Al(C6F5)3 to generate catalysts that polymerize ethylene. The polymerization of ethylene using these novel compounds is discussed. The novel activation method is confirmed by the X-ray crystallography studies of the methallyl analogs.