436845-29-3Relevant academic research and scientific papers
The intermolecular Pauson-Khand reaction of sugar-derived azaenynes: A case of total diastereoselectivity
Areces, Pilar,Carrasco, Esther,Plumet, Joaquin
, p. 197 - 202 (2006)
Sugar azaenynes 1a and 1b, easily available from D-glucal and D-galactal, respectively, react with norbornene and norbornadiene under Pauson-Khand conditions to give the intermolecular adducts as major or exclusive product. In all cases only one diastereo
Synthesis of enantiopure 3-azabicyclo[3.3.0]octen-7-one derivatives via intramolecular Pauson-Khand cycloaddition reaction using tri-O-acetyl-D-glucal as starting material
Areces, Pilar,Angeles Duran,Plumet, Joaquin,Hursthouse, Michael B.,Light, Mark E.
, p. 3506 - 3509 (2007/10/03)
Some N-substituted-3-azabicyclo[3.3.0]octen-7-one derivatives have been synthesized in an enantiomerically pure form starting from tri-O-acetyl-D-glucal via intramolecular Pauson-Khand (IPK) cycloaddition.
