4370-76-7Relevant academic research and scientific papers
KINETICS AND MECHANISM OF THE FORMATION OF AZOMETHINE DYES IN AQUEOUS ORGANIC MEDIUM. 1. KINETICS OF THE FORMATION OF DYES FROM THE SERIES OF CH ACIDS AND 4-AMINO-3-METHYL-N-ETHYL-N-(β-METHYLSULFONAMIDOETHYL)ANILINE
Movchan, A. I.,Yablokova, E. V.,Kulakov, A. A.,Kazymov, A. V.,Chmutova, G. A.
, p. 301 - 306 (2007/10/02)
The rate constants for the oxidative coupling of hydrophobic color-forming components with 4-amino-3-methyl-N-ethyl-N-(4-methylsulfonamidoethyl)aniline and concurrent deamination in 50percent aqueous dioxane were determined by spectrophotometric methods in relation to the pH of the medium.The capacity for coupling decreases in the following order: Derivatives of 1-hydroxy-2-naphthoic acid, 1-trichlorophenyl-3-benzoylaminopyrazolin-5-one, and pivaloylacetanilide.Deamination affords the strongest competition to coupling when pivaloylacetanilide is used.
A Frontier Orbital Study of Substituent Effects in the Deamination of N-Substitued Quinone Di-imines
Grampp, Guenter
, p. 2001 - 2004 (2007/10/02)
The substituent effects on the rate constant of the acid and alkaline deamination of quinone di-imines are explained, using the frontier orbital (FO) perturbation theory.The main contributions to the pertubation energy are electrostatic and orbital interactions.The alkaline deamination is both orbital and charge controlled, whereas the acid deamination is only an orbital-controlled reaction.
