437606-72-9

Basic information

• Product Name: trans-[PtCl₄(NH=C(Et)ON=C(OH)C₆H₄Cl-p)2]
• CAS NO: 437606-72-9
• Molecular Weight: 790.217
• Mol File: 437606-72-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[PtCl₄(NH=C(Et)ON=C(OH)C₆H₄Cl-p)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[PtCl₄(NH=C(Et)ON=C(OH)C₆H₄Cl-p)2](437606-72-9)
• EPA Substance Registry System: trans-[PtCl₄(NH=C(Et)ON=C(OH)C₆H₄Cl-p)2](437606-72-9)

Safety Data

• Hazardous Substances Data: 437606-72-9(Hazardous Substances Data)

Upstream product

• 342028-87-9 trans-[PtCl₄(propiononitrile)2] 
• 1613-88-3 4-chloro-N-hydroxybenzamide 

Relevant articles and documents

Novel reactivity mode of hydroxamic acids: A metalla-pinner reaction

The reaction between the nitrile complex trans-[PtCl4(EtCN)2] and benzohydroxamic acids RC6H4C(=O)NHOH (R = p-MeO, p-Me, H, p-Cl, o-HO) proceeds smoothly in CH2Cl2 at ～45°C for 2-3 h (sealed tube) or under focused 300 W microwave irradiation for ～15 min at 50°C giving, after workup, good yields of the imino complexes [PtCl4{NH=C(Et)ON=C(OH)(C6H4R)}2] which derived from a novel metalla-Pinner reaction. The complexes [PtCl4- {NH=C(Et)ON=C(OH)(C6H4R)}2] were characterized by elemental analyses (C, H, N), FAB mass spectrometry, and IR and 1H and 13C{1H} spectroscopies, and [PtCl4{NH=C(Et)ON=C(OH)(Ph)}2] (as the bis-dimethyl sulfoxide solvate), by X-ray single-crystal diffraction. The latter disclosed its overall trans-configuration with the iminoacyl species in the hydroximic tautomeric form in E-configuration which is held by N-H···N hydrogen bond between the imine =NH atom and the hydroximic N atom.