4378-84-1Relevant academic research and scientific papers
Efficient synthesis of 4-halo-D3-trishomocubane derivatives
Levandovskiy, Igor A.,Gaidai, Alexandr V.,Zhyhadlo, Yevheniia Y.,Sharapa, Dmitry I.,Shishkin, Oleg V.,Shishkina, Svitlana V.,Rassukana, Yuliya V.
, p. 373 - 383 (2019/01/03)
Reaction of Cs-trishomocubane-8,11-diol with hydrohalic acids results in haloalcohols – 4,7-disubstituted derivatives of D3-trishomocubane. The reaction involves the rearrangement of the trishomocubane skeleton and the stereoselective formation of 4,7-D3-trishomocubanediol and 5‐oxahexacyclo[5.4.1.02,6.03,10.04,8.09,12]-dodecane as side products. The mechanism of the rearrangement was proposed. 7-Halo-D3-trishomocuban-4-ols were oxidized to the corresponding haloketones. The structure of the major isomers of the haloketones was confirmed through X-ray analysis.
A NOVEL, VERSATILE SYNTHETIC APPROACH TO LINEARLY FUSED TRICYCLOPENTANOIDS via PHOTO-THERMAL OLEFIN METATHESIS
Mehta, Goverdhan,Srikrishna, A.,Reddy, A. Veera,Nair, Mangalam S.
, p. 4543 - 4559 (2007/10/02)
Fifteen examples of a new, speedy and general approach to linearly fused tricyclopentanoids bearing the tricyclo2,6>undecane (triquinane) frame of high contemporary interest is delineated.The key concept in our synthetic sequence to tri
The reaction of potassium iodide in polyhydrogen fluoride-pyridine with two cage diols. A simple synthesis of tetracyclo4,11.05,9>undeca-2,6-diene ('homohypostrophene')
Dong, Dao Cong,Edward, John T.
, p. 1324 - 1326 (2007/10/02)
The diol 2 was converted by treatment with potassium iodide in polyhydrogen fluoride-pyridine into a mixture of the diiodide 5 and homohypostrophene 6.The diol 10 under the same conditions gave the ether 14.Treatment of the mixture of 5 and 6 with sodium in boiling tetrahydrofuran gave an easily-separable mixture of 6 and 7.
