438053-17-9Relevant academic research and scientific papers
Generation and in situ Diels-Alder reactions of activated nitroethylene derivatives
Wade, Peter A.,Murray Jr., James K.,Shah-Patel, Sharmila,Carroll, Patrick J.
, p. 2585 - 2588 (2007/10/03)
Dienes readily undergo Diels-Alder reaction with CH2=C(NO2)SO2Ph (2a), CH2=C(NO2)CO2Et (2b), and CH2=C(NO2)COPh (2c), all observed in situ by 1H NMR. The cycloadducts of 2a undergo SRN1 reactions.
Competing Diels-Alder reactions of activated nitroethylene derivatives and [3,3]-sigmatropic rearrangements of the cycloadducts
Wade, Peter A.,Murray Jr., James K.,Shah-Patel, Sharmila,Le, Hung T.
, p. 1090 - 1091 (2007/10/03)
Diels-Alder reaction of nitroethylene derivatives with cyclohexa-1,3-diene afforded three pericyclic products some of which could be converted to othersvia a new [3,3]-sigma-tropic rearrangement orvia a Claisen rearrangement.
