439129-39-2Relevant academic research and scientific papers
Dicobalt Octacarbonyl Promoted Rearrangement of 4-Isoxazolines to Acylaziridines: Dramatic Rate Acceleration with Very High Substrate Tolerance
Ishikawa, Teruhiko,Kudoh, Takayuki,Yoshida, Juri,Yasuhara, Ayako,Manabe, Shinobu,Saito, Seiki
, p. 1907 - 1910 (2002)
(Matrix Presented) Dicobalt octacarbonyl [Co2(CO)8] in acetonitrile at 75 °C triggers the cleavage of the N-O bond of 4-isoxazolines (1) to bring about the valence rearrangement to 2-acylaziridines (2). The isoxazolines were stable a
