4392-77-2Relevant academic research and scientific papers
Amphiphilic viologen: Electrochemical generation of organic reductant and pd-catalyzed reductive coupling of aryl halides in water
Kuroboshi, Manabu,Yamamoto, Takashi,Tanaka, Hideo
, p. 197 - 200 (2013)
Electroreduction of 1,1′-bis(methoxyethoxyethoxyethyl)-4,4′- bipyridinium tosylate generated amphiphilic organic reductants, which promoted the Pd-catalyzed reductive coupling of aryl bromides in water to give the corresponding biaryls. The yields and selectivity of biaryls depended on the length of ethyleneoxy groups and substituents of the aryl bromides. Georg Thieme Verlag Stuttgart · New York.
Viologen as catalytic organic reductant: Electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system
Kuroboshi, Manabu,Shiba, Takuya,Tanaka, Hideo
, p. 3666 - 3668 (2013/07/05)
Viologen can be used as an in situ recyclable organic reductant. Pd-catalyzed electrochemical reductive coupling of aryl bromides was performed by using a catalytic amount of viologen to afford the corresponding biaryls in good to moderate yields.
