439599-07-2Relevant academic research and scientific papers
Platinum complex-catalyzed hydrosilylation and isomerization of methylenecyclopropane derivatives. Effect of structures of the substrate and catalyst
Itazaki, Masumi,Nishihara, Yasushi,Osakada, Kohtaro
, p. 6889 - 6895 (2002)
PtI2(PPh3)2 catalyzes hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3, HSiPh3, HSiEt2Ph, HSiPhCl2, and HSiCl3 under solvent-free conditions at 140°
Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane
Nishihara, Yasushi,Itazaki, Masumi,Osakada, Kohtaro
, p. 2059 - 2061 (2007/10/03)
PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of S
