439659-89-9

Upstream product

• 3839-31-4 dimethyl(phenyl)silyl lithium 
• 160731-01-1 RuCl₂(CO)(PiPr₃)2 

Downstream Products

• 439659-90-2 Ru[C(C₆H₅)CHSi(CH₃)2C₆H₅]ClCO(P[CH(CH₃)2]3)2 
• 104834-20-0 [Ru((E)-CHCH(C₆H₅))(Cl)(CO)(P(iPr)3)2] 

Relevant academic research and scientific papers

Ruthenium-catalyzed hydrosilylation of terminal alkynes: Stereodivergent synthesis of (E)- and (Z)-alkenylsilanes

Stereodivergent hydrosilylation of terminal alkynes (RC≡CH; R = Ph, p-tolyl, Cy, n-hexyl) with hydrosilanes (HSiMe2Ar; Ar=Ph, 3,5-(CF3)2C6H3, 4-CF3C6H4, 4-MeOC6H4) has been examined using ruthenium catalysts. (E)-selective reactions giving (E)-RCH=CHSiMe2Ar proceed in over 99% selectivity in the presence of a catalytic amount of RuHCl(CO)(PPh3)3. On the other hand, (Z)-selective reactions are successfully conducted in 91-99% selectivity by using Ru(SiMe2Ph)Cl(CO)(PPri3)2 as the catalyst. All reactions readily proceed at room temperature in high yields. (E)- and (Z)-styrylsilanes having a SiMe2 [C6H3-3,5-(CF3)2] group serve as good cross-coupling reagents with p-iodotoluene in the presence of tetrabutylammonium fluoride and [Pd(η3-allyl) Cl]2 catalyst.