439667-21-7Relevant academic research and scientific papers
Regio- And Stereoselective Addition of HO/OOH to Allylic Alcohols
Wang, Xiao-Tao,Han, Wei-Bo,Chen, Hui-Jun,Zha, Qinghong,Wu, Yikang
, p. 10007 - 10021 (2020/08/28)
A range of allylic alcohols are shown to readily react with ethereal H2O2 in the presence of catalytic amounts of Na2MoO4-gly or MoO2(acac)2, affording the C═C trans hydroxylation-hydroperoxylation products in good yields with high regio- and stereoselect
THE SYNTHESIS OF CHIRAL ISOPROPYLIDENE DERIVATIVES OF 1,2,3-CYCLOHEXANETRIOLS BY ENZYMATIC DIFFERENTIATION
Dumortier, L.,Eycken, J. Van der,Vandewalle, M.
, p. 3201 - 3204 (2007/10/02)
2,3-O-Isopropylidene-1-cyclohexanol chiral building blocks have been prepared with high enantiomeric purities by enzymatic hydrolysis of their racemic acetates or n.butyrates.
ON STEREOCHEMISTRY OF OSMIUM TETRAOXIDE OXIDATION OF ALLYLIC ALCOHOL SYSTEMS. EMPIRICAL RULE
Cha, J. K.,Christ, W. J.,Kishi, Y.
, p. 2247 - 2256 (2007/10/02)
An empirical formulation is presented to predict the stereochemistry of major osmylation products of allylic alcohols and their derivatives.
