440085-36-9

Basic information

• Product Name: C₂₃H₂₆O₃
• CAS NO: 440085-36-9
• Molecular Weight: 350.458
• Mol File: 440085-36-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₃H₂₆O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₃H₂₆O₃(440085-36-9)
• EPA Substance Registry System: C₂₃H₂₆O₃(440085-36-9)

Safety Data

• Hazardous Substances Data: 440085-36-9(Hazardous Substances Data)

Relevant articles and documents

Notable substituent effects on the rate constant of thermal denitrogenation of cyclic azoalkanes: Strong evidence for a stepwise denitrogenation mechanism

The thermal denitrogenation rates (k) of a series of 7,7-dimethoxy-1,4- diaryl-2,3-diazabicyclo[2.2.1]hept-2-ene derivatives 2 with a variety of aryl groups (p-CNC6H4, C6H5, p-MeC 6H4, p-MeOC6H4) were determined to investigate the denitrogenation mechanism. A linear correlation (r = 0.988) between the relative rate-constant (log krel) of the denitrogenation reaction and Arnold's σ α parameter for benzylic-type radical-stabilization was observed. However, the relative rate-constant was not correlated with the substituent effect on the lifetime of the resulting singlet diradicals DR2. These results indicate that the rate-determining step of denitrogenation of 7,7-dimethoxy-2,3-diazabicyclo[2.2. 1]hept-2-ene derivatives involves stepwise C-N bond cleavage. CSIRO 2010.