440362-85-6

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 593-60-2 Vinyl bromide 

Downstream Products

• 485386-75-2 ((2S,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-vinyl-tetrahydro-pyran-3-yloxy)-((2R,3R,4R,5R,6S)-4,5-bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane 
• 1108732-44-0 (2R,3R,4R,5S,6S)-3,4-bis(benzyloxy)-2-(benzyloxymethyl)-5-(4-methoxybenzyloxy)-6-vinyltetrahydro-2H-pyran 
• 135561-09-0 C₂₈H₃₂O₆ 

Relevant academic research and scientific papers

Highly stereoselective synthesis of C-vinyl pyranosides via a Pd 0-mediated cycloetherification of 1-acetoxy-2,3-dideoxy-oct-2-enitols

Oct-2-enitols undergo a Pd0-mediated cyclization to produce C-vinyl α-gluco- and α-galactopyranosides, and C-vinyl β-mannopyranoside in good yield and with high stereoselectivity. While substrate control demonstrates a clear stereochemical pref

Synthesis of hybrids of D-glucose and D-galactose with pyrrolidine-based iminosugars as glycosidase inhibitors

Sugar-iminosugar hybrid molecules made up of D-glucose and D-galactose with pyrrolidine-based iminosugars, viz. 1,4-dideoxy-1,4-imino-L-xylitol and 1,4-dideoxy-1,4-imino-L-lyxitol, are synthesized from glycal epoxides and found to be moderate glycosidase

C-Glycosides to fused polycyclic ethers

This manuscript describes the synthesis of fused polycyclic ethers from the coupling of C-glycoside forming reactions with ring closing metathesis and acid mediated annulation reactions.