440369-08-4Relevant articles and documents
Intramolecular cyclization of benzyl-substituted cyclopentadienyl titanum dichlorides promoted by boron tribromide
Qian, Yanlong,Huang, Jiling,Ding, Kai,Zhang, Yue,Huang, Qinglan,Chen, Xiao Ping,Chan, Albert S.C,Wong, Wing Tak
, p. 59 - 64 (2002)
Intramolecular cyclization of α,α-alkyl-ortho-methoxybenzylcyclopentadienyl titanium complexes to form titanoxacycle complexes promoted by BBr3 has been studied. A probable two-step mechanism involving halogen exchange and intramolecular elimination was proposed. Four related benzyl-substituted cyclopentadienyl titanium complexes have been studied by X-ray crystallography.