440635-16-5

Upstream product

• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 
• 440635-15-4 (4aR,6S,7R,8aS)-6-{4-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-6-methyl-oxepan-2-yl]-but-2-ynyl}-2,2-di-tert-butyl-7-(tert-butyl-dimethyl-silanyloxy)-hexahydro-1,3,5-trioxa-2-sila-naphthalene 
• 440635-06-3 Trifluoro-methanesulfonic acid (2R,3S,6R,7S)-6-benzyloxy-7-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-6-methyl-oxepan-2-ylmethyl ester 
• 440635-12-1 (4aR,6S,7R,9aS)-2,2-Di-tert-butyl-6-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-hexahydro-1,3,5-trioxa-2-sila-benzocyclohepten-7-ol 
• 440635-11-0 C₃₃H₅₀O₅Si₂ 
• 440635-10-9 2,2-di-tert-butyl-6-(tert-butyl-diphenyl-silanyloxymethyl)-7-methylene-hexahydro-1,3,5-trioxa-2-sila-benzocycloheptene 
• 440635-09-6 2,2-di-tert-butyl-6-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-1,3,5-trioxa-2-sila-benzocyclohepten-7-one 
• 440635-08-5 2,2-di-tert-butyl-6-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-1,3,5-trioxa-2-sila-naphthalen-7-one 
• 440635-05-2 Trifluoro-methanesulfonic acid (4aR,6S,7R,8aS)-2,2-di-tert-butyl-7-(tert-butyl-dimethyl-silanyloxy)-hexahydro-1,3,5-trioxa-2-sila-naphthalen-6-ylmethyl ester 
• 1054661-40-3 (4aR,6S,7R,8aS)-2,2-Di-tert-butyl-7-(tert-butyl-dimethyl-silanyloxy)-6-(3-trimethylsilanyl-prop-2-ynyl)-hexahydro-1,3,5-trioxa-2-sila-naphthalene 
• 440635-13-2 (4aR,6S,7R,9aS)-7-Benzyloxy-6-benzyloxymethyl-2,2-di-tert-butyl-7-methyl-hexahydro-1,3,5-trioxa-2-sila-benzocycloheptene 
• 440635-07-4 (4aR,6S,7R,8aS)-2,2-Di-tert-butyl-7-(tert-butyl-dimethyl-silanyloxy)-6-prop-2-ynyl-hexahydro-1,3,5-trioxa-2-sila-naphthalene 
• 440635-14-3 (2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-hydroxymethyl-6-methyl-oxepan-3-ol 
• 440635-19-8 (4aR,6S,7R,9aS)-2,2-Di-tert-butyl-6-hydroxymethyl-7-methyl-hexahydro-1,3,5-trioxa-2-sila-benzocyclohepten-7-ol 

Downstream Products

• 440635-18-7 (4aR,5aS,6aR,7aS,10R,11S,12aR,13aS,14aR,15aS)-10-Benzyloxy-11-benzyloxymethyl-2,2-di-tert-butyl-10-methyl-dodecahydro-1,3,5,7,12,14-hexaoxa-2-sila-cyclohepta[b]naphthacene-6a,13a-diol 
• 440635-21-2 (4aR,5aS,6aR,7aS,10R,11S,12aR,13aS,14aR,15aS)-10-Benzyloxy-11-benzyloxymethyl-2,2-di-tert-butyl-6a,13a-dimethoxy-10-methyl-hexadecahydro-1,3,5,7,12,14-hexaoxa-2-sila-cyclohepta[b]naphthacene 
• 440635-17-6 1-((2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-6-methyl-3-triethylsilanyloxy-oxepan-2-yl)-4-((4aR,6S,7R,8aS)-2,2-di-tert-butyl-7-triethylsilanyloxy-hexahydro-1,3,5-trioxa-2-sila-naphthalen-6-yl)-butane-2,3-dione 

Relevant academic research and scientific papers

Synthetic studies of yessotoxin, a polycyclic ether implicated in diarrhetic shellfish poisoning: Convergent synthesis of the BCDE ring system via an alkyne intermediate

A convergent synthetic route to the BCDE ring system of yessotoxin, a polycyclic ether marine toxin related to diarrhetic shellfish poisoning, has been developed. The key feature of the present synthesis is the alkylation of acetylene with the B and E rin