440650-46-4Relevant academic research and scientific papers
Synthesis of ortho-perfluoroalkyl phenones from hemifluorinated enones as key building blocks
Chanteau, Frédéric,Plantier-Royon, Richard,Haufe, Günter,Portella, Charles
, p. 9049 - 9053 (2006)
The title compounds are prepared by cycloaddition of perfluoroalkenyl ketones and 1,3-dienes, with a subsequent aromatization by basic dehydrofluorination. The perfluoroalkenyl ketones were prepared by the reaction of perfluoroorganometallic reagents with
Dienophilic reactivity of perfluoroalkenyl ketones in Diels-Alder reactions
Chanteau, Frédéric,Essers, Michael,Plantier-Royon, Richard,Haufe, Günter,Portella, Charles
, p. 1677 - 1680 (2007/10/03)
Perfluoroalkenyl ketones, obtained by reaction of perfluoroorganometallic reagents with acylsilanes, are shown to be versatile dienophiles in Diels-Alder reactions with various dienes.
