440677-16-7

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 440677-15-6 (S)-5-{(2E,4E)-(S)-6-Hydroxy-2,5-dimethyl-1-methylene-8-[(2R,4R,5R)-4-methyl-5-((E)-1-methyl-3-triisopropylsilanyloxy-propenyl)-tetrahydro-furan-2-yl]-octa-2,4-dienyl}-dihydro-furan-2-one 
• 13154-24-0 triisopropylsilyl chloride 
• 440677-08-7 (E)-3-((2R,3R,5R)-5-Allyl-3-methyl-tetrahydro-furan-2-yl)-but-2-en-1-ol 
• 440677-09-8 [(E)-3-((2R,3R,5R)-5-Allyl-3-methyl-tetrahydro-furan-2-yl)-but-2-enyloxy]-triisopropyl-silane 
• 440677-11-2 3-[(2R,4R,5R)-4-Methyl-5-((E)-1-methyl-3-triisopropylsilanyloxy-propenyl)-tetrahydro-furan-2-yl]-propionaldehyde 
• 440677-10-1 3-[(2R,4R,5R)-4-Methyl-5-((E)-1-methyl-3-triisopropylsilanyloxy-propenyl)-tetrahydro-furan-2-yl]-propan-1-ol 
• 440677-12-3 {1-Methyl-4-[(2R,4R,5R)-4-methyl-5-((E)-1-methyl-3-triisopropylsilanyloxy-propenyl)-tetrahydro-furan-2-yl]-2-oxo-butyl}-phosphonic acid diethyl ester 
• 440677-14-5 (S)-5-{(2E,4E)-2,5-Dimethyl-1-methylene-8-[(2R,4R,5R)-4-methyl-5-((E)-1-methyl-3-triisopropylsilanyloxy-propenyl)-tetrahydro-furan-2-yl]-6-oxo-octa-2,4-dienyl}-dihydro-furan-2-one 

Relevant academic research and scientific papers

Asymmetric construction of the azaspiro[5.5]undec-8-ene system towards gymnodimine synthesis

In the course of the synthetic studies on gymnodimine, a potent shellfish toxin, the asymmetric construction of the azaspirocyclic part was achieved by the (-)-siam·Cu(SbF6)2 complex catalyzed intermolecular Diels-Alder reaction in high exo- and enantioselectivities.