441044-58-2Relevant academic research and scientific papers
A Ramberg-Baecklund approach to the synthesis of C-glycosides, C-linked disaccharides, and C-glycosyl amino acids
Paterson, Duncan E.,Griffin, Frank K.,Alcaraz, Marie-Lyne,Taylor, Richard J. K.
, p. 1323 - 1336 (2007/10/03)
Synthetic applications of exo-glycals, derived from S-glycoside dioxides using the Meyers variant of the Ramberg-Baecklund rearrangement, are described. These include a formal synthesis of a β-glycosidase inhibitor 12 and an efficient route to spirocyclic glucose derivatives 17 and 18. The synthesis of C-linked disaccharides 24, 31, and 38 and the C-glycosyl amino acid 49 using the Ramberg-Baecklund rearrangement is also reported. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
Ramberg - Backlund approaches to the synthesis of C-linked disaccharides
Griffin, Frank K.,Paterson, Duncan E.,Taylor, Richard J. K.
, p. 2939 - 2942 (2007/10/03)
Readily available S-glycoside dioxides were utilized in a Ramberg- Backlund rearrangement for the construction of C-linked disaccharides. This approach is ideally suited to analogue synthesis simply by variation of the alkylating agent, and is illustrated
