441071-64-3Relevant academic research and scientific papers
Reactions of an osmium-elongated dihydrogen complex with terminal alkynes: Formation of novel bifunctional compounds with amphoteric nature
Barrio, Pilar,Esteruelas, Miguel A.,O?ate, Enrique
, p. 2491 - 2503 (2008/10/08)
The reactions of osmium-elongated dihydrogen complex with terminal alkynes were analyzed. The distribution of ligands around the osmium atom can be described as a distorted trigonal bipyramid with apical phosphines and inequivalent angles within the Y-shaped equatorial plane. The transformation of alkyne-carbene appears to occur via alkynyl species involving two dissociation-addition processes, where the oxime ligand plays a major role.
