441311-03-1

Basic information

• Product Name: PENT-4-ENYL-6-O-T-BUTYLDIPHENYLSILYL-D-GLUCOPYRANOSIDE
• Synonyms: PENT-4-ENYL-6-O-T-BUTYLDIPHENYLSILYL-D-GLUCOPYRANOSIDE
• CAS NO: 441311-03-1
• Molecular Formula: C₂₇H₃₈O₆Si
• Molecular Weight: 486.67
• Mol File: 441311-03-1.mol

Chemical Properties

• Boiling Point: 570.6°C at 760 mmHg
• Flash Point: 298.9°C
• Appearance: /
• Density: 1.15g/cm³
• Vapor Pressure: 7.37E-14mmHg at 25°C
• Refractive Index: 1.566
• CAS DataBase Reference: PENT-4-ENYL-6-O-T-BUTYLDIPHENYLSILYL-D-GLUCOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PENT-4-ENYL-6-O-T-BUTYLDIPHENYLSILYL-D-GLUCOPYRANOSIDE(441311-03-1)
• EPA Substance Registry System: PENT-4-ENYL-6-O-T-BUTYLDIPHENYLSILYL-D-GLUCOPYRANOSIDE(441311-03-1)

Safety Data

• Hazardous Substances Data: 441311-03-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C27H38O6Si/c1-5-6-13-18-31-26-25(30)24(29)23(28)22(33-26)19-32-34(27(2,3)4,20-14-9-7-10-15-20)21-16-11-8-12-17-21/h5,7-12,14-17,22-26,28-30H,1,6,13,18-19H2,2-4H3/t22-,23-,24+,25-,26u/m1/s1

Upstream product

• 604-69-3 β-D-glucose pentaacetate 
• 821-09-0 n-Pent-4-enyl alcohol 
• 182074-52-8 pent-4-enyl α,β-D-glucopyranoside 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 136755-18-5 pent-4-enyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldiphenylsilyl-α-D-glucopyranoside 
• 127570-61-0 2,3,4-tri-O-benzyl-N-(benzyl N-benzyloxycarbonyl-L-β-aspartyl)-α-D-glucopyranosylamine 
• 127594-29-0 2,3,4-tri-O-benzyl-N-(benzyl N-benzyloxycarbonyl-L-β-aspartyl)-6-O-tert-butyldiphenylsilyl-α-D-glucopyranosylamine 
• 127570-64-3 N-acetyl-2,3,4-tri-O-benzyl-N-(benzyl N-benzyloxycarbonyl-L-β-aspartyl)-6-O-tert-butyldiphenylsilyl-α-D-glucopyranosylamine 
• 127570-65-4 pent-4-enyl 2,3,4-tri-O-benzoyl-α-D-glucopyranoside 
• 127594-30-3 pent-4-enyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,5-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-glucopyranoside 
• 441311-05-3 [2-((2S,3R,4R,5S)-3,4,5-Tris-benzyloxy-2-hydroxymethyl-piperidin-1-yl)-ethyl]-carbamic acid (2S,3R,4R,5S)-1-(2-amino-ethyl)-3,4,5-tris-benzyloxy-piperidin-2-ylmethyl ester 
• 441310-90-3 4-(3-Methoxy-4-{2-[(2S,3R,4R,5S)-3,4,5-tris-benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-piperidin-1-yl]-ethylcarbamoyloxymethyl}-phenoxy)-butyric acid methyl ester 
• 441310-91-4 4-(3-Methoxy-4-{2-[(2S,3R,4R,5S)-3,4,5-tris-benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-piperidin-1-yl]-ethylcarbamoyloxymethyl}-phenoxy)-butyric acid 
• 441310-86-7 [3,4,5-tris-benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-piperidin-1-yl]-carbamic acid 9H-fluoren-9-ylmethyl ester 
• 441310-83-4 Methanesulfonic acid (1R,2S,3R,4S)-2,3,4-tris-benzyloxy-1-(tert-butyl-diphenyl-silanyloxymethyl)-5-methanesulfonyloxy-pentyl ester 
• 441310-88-9 2-[(2S,3R,4R,5S)-3,4,5-Tris-benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-piperidin-1-yl]-ethylamine 
• 441310-84-5 (2S,3R,4R,5S)-1-Allyl-3,4,5-tris-benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-piperidine 
• 441310-82-3 (2S,3R,4R,5R)-2,3,4-Tris-benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-hexane-1,5-diol 

Relevant articles and documents

Solid-phase synthesis of a new class of oligosaccharide analogues based on azasugars

A strategy for the solid-phase synthesis of a new class of oligosaccharide analogues based on coupling of azasugar building blocks via carbamate bonds is described.

Application of n-pentenyl glycosides in the regio- and stereo-controlled synthesis of α-linked N-glycopeptides

The N-glycopeptides α-Glc-(1→Asn and α-Glc-(1→6)-β-Glc-(1→6)-α-Glc-(1→Asn have been synthesized efficiently from pent-4-enyl D-glucopyranoside derivatives. The methodology illustrates (a) a novel route for formation of the N-α-D-glucosyl-asparagine link,