441350-29-4Relevant academic research and scientific papers
Synthetic studies on cyathin terpenoids: Enantioselective synthesis of the tricyclic core of cyathin through intramolecular Heck cyclisation
Drege, Emmanuelle,Tominiaux, Cyrille,Morgant, Georges,Desmaele, Didier
, p. 4825 - 4840 (2006)
An enantioselective synthesis of the tricyclic ketone (+)-5, which displays the carbon core of NGF-inducing cyathane diterpenes, has been completed according to a strategy in which the key step was the intramolecular Heck reaction of the AC subunit 49 est
High pressure activation in the asymmetric Michael addition of chiral imines to alkyl and aryl crotonates
Camara, Cheikhou,Joseph, Delphine,Dumas, Fran?oise,D'Angelo, Jean,Chiaroni, Angèle
, p. 1445 - 1448 (2007/10/03)
High pressure-mediated Michael addition of chiral imines derived from 2-methylcyclopentanone, 2-methylcyclohexanone and optically active 1-phenylethylamine, to methyl and phenyl crotonates was investigated. The corresponding adducts were obtained in fair yields and with a high degree of regio-, diastereo- and enantioselectivity.
