441353-07-7Relevant articles and documents
Reactions of nitroxides with metalloporphyrin alkyls bearing beta hydrogens: Aliphatic carbon-carbon bond activation by metal centered radicals
Chan, Kin Shing,Mak, Kin Wah,Tse, Man Kin,Yeung, Siu Kwan,Li, Bao Zhu,Chan, Yun Wai
, p. 399 - 407 (2008/03/18)
Nitroxide-induced beta-hydrogen atom abstraction and beta-elimination of rhodium porphyrin alkyls have been observed. Rhodium(II) porphyrin radical were proposed intermediates to form first and subsequently reacted via aliphatic carbon-carbon bond activation with alkyl substituted nitroxides to yield rhodium porphyrin alkyl complexes.