442155-84-2

Basic information

• Product Name: 5-Hexyn-1-ol, 6-(2-nitrophenyl)-
• CAS NO: 442155-84-2
• Molecular Formula: C12H13NO3
• Molecular Weight: 219.24
• Mol File: 442155-84-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-Hexyn-1-ol, 6-(2-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexyn-1-ol, 6-(2-nitrophenyl)-(442155-84-2)
• EPA Substance Registry System: 5-Hexyn-1-ol, 6-(2-nitrophenyl)-(442155-84-2)

Safety Data

• Hazardous Substances Data: 442155-84-2(Hazardous Substances Data)

Upstream product

• 928-90-5 5-hexyl-1-ol 
• 609-73-4 o-nitroiodobenzene 

Downstream Products

• 665033-59-0 tert-butyl-dimethyl-[6-(2-nitro-phenyl)-hex-5-ynyloxy]-silane 
• 665033-61-4 N-isopropyl-2-(6-tert-butyldimethylsilyloxy-1-hexynyl)aniline 
• 442155-90-0 6-{2-(4-methylphenylsulfonamido)phenyl}hex-5-ynyl-4-methylbenzenesulfonate 
• 442155-88-6 2-[6-(p-toluenesulfonyloxy)-1-hexynyl]aniline 
• 205642-01-9 9-(toluene-4-sulphonyl)-2,3,4,9-tetrahydro-1H-carbazole 
• 442155-86-4 2-[6-(p-tolylsulfonyloxy)-1-hexynyl]nitrobenzene 

Relevant articles and documents

Divergent Pd(ii) and Au(iii) mediated nitroalkynol cycloisomerizations

A new cycloisomerization reaction comprising the simultaneous addition of nitro and alcohol groups across CC leading to skeletally diverse small molecules is documented.

Efficient construction of indole rings from 2-ethynylaniline derivatives catalyzed by copper(II) salts and its application to the tandem cyclization reactions

The efficient cyclization reactions of the N-methanesulfonyl or N-ethoxycarbonyl derivatives of 2-ethynylanilines, functionalized on the benzene ring and/or the acetylene terminal into indoles catalyzed by either Cu(OTf)2 or Cu(OAc)2 are accomplished. The application of this reaction to the tandem cyclization reaction is also described.