4422-06-4 Usage
Description
(1E)-cyclododecane-1,2-dione oxime is a versatile chemical compound known for its wide range of industrial applications. It is characterized by its ability to enhance the performance and durability of materials and products, making it a valuable component in various industries.
Uses
Used in Polymer and Plastics Industry:
(1E)-cyclododecane-1,2-dione oxime is used as a stabilizer and inhibitor for the production of polymers and plastics. It plays a crucial role in preventing degradation and improving the overall quality of these materials.
Used as a Chemical Intermediate:
(1E)-cyclododecane-1,2-dione oxime serves as a chemical intermediate in the synthesis of other compounds, contributing to the creation of a diverse range of products.
Used in Epoxy Resin Industry:
(1E)-cyclododecane-1,2-dione oxime functions as a curing agent for epoxy resins, which are essential in various applications due to their strong adhesive and coating properties.
Used in Adhesives, Coatings, and Sealants Production:
(1E)-cyclododecane-1,2-dione oxime is utilized in the production of adhesives, coatings, and sealants, where its properties contribute to the enhanced performance and durability of these products.
Used in Automotive Industry:
(1E)-cyclododecane-1,2-dione oxime has potential applications in the automotive industry, where it can improve the performance and longevity of various components and materials.
Used in Construction Industry:
In the construction sector, this chemical compound can be employed to enhance the durability and performance of building materials, contributing to more robust and long-lasting structures.
Used in Electronics Industry:
(1E)-cyclododecane-1,2-dione oxime also finds potential use in the electronics industry, where it can improve the quality and reliability of electronic components and devices.
Check Digit Verification of cas no
The CAS Registry Mumber 4422-06-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,4,2 and 2 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 4422-06:
(6*4)+(5*4)+(4*2)+(3*2)+(2*0)+(1*6)=64
64 % 10 = 4
So 4422-06-4 is a valid CAS Registry Number.
4422-06-4Relevant articles and documents
Enolate-Based Regioselective Anti-Beckmann C-C Bond Cleavage of Ketones
Ma?ek, Tomá?,Jahn, Ullrich
, p. 11608 - 11632 (2021/09/02)
The Baeyer-Villiger or Beckmann rearrangements are established methods for the cleavage of ketone derivatives under acidic conditions, proceeding for unsymmetrical precursors selectively at the more substituted site. However, the fragmentation regioselectivity cannot be switched and fragmentation at the less-substituted terminus is so far not possible. We report here that the reaction of ketone enolates with commercial alkyl nitrites provides a direct and regioselective way of fragmenting ketones into esters and oximes or ω-hydroxyimino esters, respectively. A comprehensive study of the scope of this reaction with respect to ketone classes and alkyl nitrites is presented. Control over the site of cleavage is gained through regioselective enolate formation by various bases. Oxidation of kinetic enolates of unsymmetrical ketones leads to the otherwise unavailable "anti-Beckmann"cleavage at the less-substituted side chain, while cleavage of thermodynamic enolates of the same ketones represents an alternative to the Baeyer-Villiger oxidation or the Beckmann rearrangement under basic conditions. The method is suited for the transformation of natural products and enables access to orthogonally reactive dicarbonyl compounds.
A remarkably simple α-oximation of ketones to 1,2-dione monooximes using the chlorotrimethylsilane-isoamyl nitrite combination
Mohammed, Abdulkarim H.A.,Nagendrappa, Gopalpur
, p. 2753 - 2755 (2007/10/03)
Ketones undergo α-oximation by NOCl formed in situ from Me3SiCl and isoamyl nitrite, either in solution or under solvent-free conditions, to produce 1,2-dione monooximes in excellent yields. The oximation is regiospecific in appropriate cases.
