4424-06-0

Basic information

• Product Name: Vat Orange 7
• Synonyms: C.I. 71105;c.i. pigment orange 43;bisbenzimidazo[2,1-b:2',1'-i]benzo[lmn][3,8]phenanthroline-8,17-dione;Vat Orange 7;dibenzimidazo[2,1-b,2,1-i]benzo[lmn]-[3,8]-phenanthroline-8,17-dione;pigment orange 43;Pigment Orange 43 (C.I.);Vat Orange 7 (C.I.)
• CAS NO: 4424-06-0
• Molecular Formula: C₂₆H₁₂N₄O₂
• Molecular Weight: 412.407
• EINECS: 224-597-4
• Mol File: 4424-06-0.mol

Chemical Properties

• Boiling Point: 531.86°C (rough estimate)
• Flash Point: 514.4 °C
• Appearance: Fine orange powder
• Density: 1.66
• Vapor Pressure: 1.87E-35mmHg at 25°C
• Refractive Index: 1.6000 (estimate)
• PKA: 1.34±0.20(Predicted)
• CAS DataBase Reference: Vat Orange 7(CAS DataBase Reference)
• NIST Chemistry Reference: Vat Orange 7(4424-06-0)
• EPA Substance Registry System: Vat Orange 7(4424-06-0)

Safety Data

• RTECS: DX1000000
• Hazardous Substances Data: 4424-06-0(Hazardous Substances Data)

Usage

Uses

Pigment Orange 43 is colorant; used in preparation of anti-UV polyethylene masterbatc.

General Description

Fine orange powder.

Air & Water Reactions

Insoluble in water.

Fire Hazard

Flash point data for Vat Orange 7 are not available. Vat Orange 7 is probably combustible.

Properties and Applications

TEST ITEMS SPECIFICATION APPEARANCE ORANGE POWDER SHADE REDDISH HEAT RESISTANCE 300 °C min LIGHT FASTNESS 7-8 ACID RESISTANCE 5 ALKALI RESISTANCE 5 FASTNESS TO BLEEDING 5 OIL ABSORPTION 40-50% SPECIFIC SURFACE 28m 2 /g DENSITY 1.50 g/cm 3 RESIDUE ON 80 MESH 5.0% max WATER SOLUBLE 1.0% max VOLATITE 105 °C 1.0% max TINTING STRENGTH 100-105 %

TEST ITEMS

SPECIFICATION

APPEARANCE

ORANGE POWDER

SHADE

REDDISH

HEAT RESISTANCE

300 °C min

LIGHT FASTNESS

7-8

ACID RESISTANCE

5

ALKALI RESISTANCE

5

FASTNESS TO BLEEDING

5

OIL ABSORPTION

40-50%

SPECIFIC SURFACE

28m 2 /g

DENSITY

1.50 g/cm 3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBLE

1.0% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

100-105 %

InChI:InChI=1/C26H12N4O2/c31-25-15-12-10-14-22-16(26(32)30-20-8-4-2-6-18(20)28-24(14)30)11-9-13(21(15)22)23-27-17-5-1-3-7-19(17)29(23)25/h1-12H

Upstream product

• 81-30-1 1,4,5,8-naphthalenetetracarboxylic dianhydride 
• 95-54-5 1,2-diamino-benzene 
• 479-27-6 naphthalene-1,8-diamine 

Relevant articles and documents

High-performance black color paste and preparation method thereof

The invention relates to the technical field of black pigments, in particular to a high-performance black color paste and a preparation method thereof. The preparation process does not need to be subjected to grinding treatment, can be highly dispersed in the low-melting-point amphiphilic solid, can effectively improve the workability and repeatability, and reduces the chromatic aberration 10% - 1000%. The preparation method disclosed by the invention causes the components to react and discolor in the kneading machine, finally obtains the black color paste, and is simple in preparation step, easy and convenient to operate, easy to prepare and good in application prospect.

Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds

Highly fused, fully conjugated aromatic compounds are interesting candidates for organic electronics. With higher crystallinity their electronic properties improve. It is shown here that the crystallization of three archetypes of such molecules—pentacenetetrone, indigo, and perinone—can be achieved hydrothermally. Given their molecular structure, this is a truly startling finding. In addition, it is demonstrated that perinone can also be synthesized in solely high-temperature water from the starting compounds naphthalene bisanhydride and o-phenylene diamine without the need for co-solvents or catalysts. The transformation can be drastically accelerated by the application of microwave irradiation. This is the first report on the hydrothermal generation of two fused heterocycles.

Green synthesis of polycyclic benzimidazole derivatives and organic semiconductors

Polycyclic benzimidazole derivatives, an important class of compounds in organic electronics and photovoltaics, were prepared using a solvent-free "green" process based on heating carboxylic acid anhydrides and arylene diamines in the presence of zinc acetate in the solid state. Products were isolated and purified directly by train sublimation of the crude reaction mixtures. The reaction conditions were optimized using various carboxylic acid anhydrides. Optical and electrochemical properties of these materials are also described.

Multicyclic benzimidazole derivatives useful as photoconductive members

A compound comprising a bisbenzamidazoleperinone of the following formula wherein each of R1, R2, R3, and R4 are the same or different and are independently selected from the group consisting of hydrogen, alkyl, aryl, hydrocarbon, which may be optionally substituted or arranged in such a way as to form a cyclic ring which can be either saturated or unsaturated and halogen.

Photoconductive members

A compound comprising a bisbenzamidazoleperinone of the following formula wherein each of R1, R2, R3, and R4 are the same or different and are independently selected from the group consisting of hydrogen, alkyl, aryl, hydrocarbon, which may be optionally substituted or arranged in such a way as to form a cyclic ring which can be either saturated or unsaturated and halogen.