442518-16-3Relevant academic research and scientific papers
Synthesis and characterization of copper (II) and nickel(II) arylcarboxylate complexes with cyanopyridines
Bajju
, p. 767 - 770 (2007/10/03)
The coper(II) and nickel(II) arylcarboxylates react with 2-, 3- and 4-cyanopyridines (CNPy) in an organic medium to give solid complexes having general formula [M(O2CR)2L] and [M(O2CR)2L2], R=o-ClC6H4-, o-OCH3 C6H4- and m-OCH3C6H4-; L=2-, 3- and 4-CNPy). All the complexes with Cu(II) arylcarboxylates are of 1:1 stoichiometry irrespective of the amount of ligand added and have been shown by physicochemical methods to be binuclear, containing bidentate bridging carboxylate group. Ni(II) arylcarboxylate complexes are mononuclear having bidentate chelating carboxylate group. Cyanopyridine moiety functions as a monodentate ligand coordinating through pyridine nitrogen atom.
