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442848-09-1

[RuH(CO)(PPh3)2(η(2)-2,4,6-tris-(2'-pyridyl)-1,3,5-triazine)][BF4] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 442848-09-1 Structure

  • Basic information

    1. Product Name: [RuH(CO)(PPh3)2(η(2)-2,4,6-tris-(2'-pyridyl)-1,3,5-triazine)][BF4]
    2. Synonyms:
    3. CAS NO:442848-09-1
    4. Molecular Formula:
    5. Molecular Weight: 1053.81
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 442848-09-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [RuH(CO)(PPh3)2(η(2)-2,4,6-tris-(2'-pyridyl)-1,3,5-triazine)][BF4](CAS DataBase Reference)
    10. NIST Chemistry Reference: [RuH(CO)(PPh3)2(η(2)-2,4,6-tris-(2'-pyridyl)-1,3,5-triazine)][BF4](442848-09-1)
    11. EPA Substance Registry System: [RuH(CO)(PPh3)2(η(2)-2,4,6-tris-(2'-pyridyl)-1,3,5-triazine)][BF4](442848-09-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 442848-09-1(Hazardous Substances Data)

442848-09-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 442848-09-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,4,2,8,4 and 8 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 442848-09:
(8*4)+(7*4)+(6*2)+(5*8)+(4*4)+(3*8)+(2*0)+(1*9)=161
161 % 10 = 1
So 442848-09-1 is a valid CAS Registry Number.

442848-09-1Relevant articles and documents

Synthetic, spectral and structural aspects of some mono- and binuclear (homo/hetero) Ru(II) hydrido carbonyl complexes

Chandra, Manish,Sahay, Abhaya Nand,Pandey, Daya Shankar,Puerta, M.Carmen,Valerga, Pedro

, p. 39 - 48 (2007/10/03)

Reactions of the poly-pyridyl bridging ligand 2,4,6-tris(2-pyridyl)-1,3,5-triazine; 2,3-bis(2-pyridyl)-pyrazine and 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (referred hereafter as tptz, bppz and bptz respectively) with [RuH(CO)Cl(PPh3)3] in methanol, gave highly stable cationic complexes with the formulation [RuH(CO)(PPh3)2(L)]+. Further, the mononuclear complex [RuH(CO)(PPh3)2(bppz)]PF6 reacted with K2PtCl4, [PdCl2(benzonitrile)2], [RuH(CO)(PPh3)2(bppz)PdCl2]PF 6, [RuH(CO)(PPh3)2(bppz)(η 6-C10 H14)RuCl](PF6) 2, [RuH(CO)(PPh3) 2(bppz)(η 6-C6Me6)Cl2Ru](PF 6)2, [RuH(CO)(PPh3)2 (bppz)(η5-C5H5) (PPh 3)Ru](PF6)2 and [RuH(CO)(PPh 3)2(bppz)Rh(η5-C5 Me5)Cl](PF6)2 in quantitative yield. The reaction products have been characterized by elemental analyses, IR, 1H-, 1H-1H-COSY, 13C-, 31P-NMR, ESMS, FAB mass spectroscopy, electronic spectra and cyclic voltammetry. Molecular structure of the representative mononuclear complex [RuH(CO)(PPh3)2(tptz)]BF4 has been confirmed by X-ray crystallography. Crystal structure determination revealed η2-coordination of the ligand tptz with the metal center. Crystal data: monoclinic, P21/n, a = 17.810(6) A?, b = 22.233(9) A?, β = 90.06(3)°, Z = 4, R = 0.078.

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