443650-54-2Relevant academic research and scientific papers
Synthesis and molecular structure of Pd2(C6F5)2[μ-P(C6F 5)CH2CH2P(C6F5)2 ]2. A rare example of P-C bond cleavage in a fluoroaryl phosphine
Heyn, Richard H.,G?rbitz, Carl Henrik
, p. 2781 - 2784 (2002)
A transition metal-mediated P-Arf cleavage in a tertiary fluoroarylphosphine was reported. The resulting dimer contained two bridging, chelated fluoroaryl phosphino-phosphido ligands. The P-Arf bond cleavage was seen as an anomaly, considering that strong electron-withdrawing groups enhance the rate of P-C(Ar) oxidative addition to low-valent transition metals. The fluoroaryl phosphino-phosphido ligand was seen as a rare example of a bent biphosphido bimetallic complex.
